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Reference IUPAC Nomenclature Reference Functional Group Priority and Suffixes

Functional Group Priority and Suffixes

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When multiple functional groups are present, the one with the highest priority (lowest number in this table) determines the suffix. All lower-priority groups are expressed as prefixes.

PriorityFunctional GroupSuffixPrefix (when not principal)
1Carboxylic acid-oic acidcarboxy-
2Ester-oate(alkoxy-carbonyl-)
3Amide-amidecarbamoyl-
4Aldehyde-aloxo- (on terminal carbon)
5Ketone-oneoxo-
6Alcohol-olhydroxy-
7Amine-amineamino-
8Alkyne-yne
9Alkene-ene
10Alkane-ane

Note on aldehydes: The carbonyl carbon of an aldehyde is always C-1, so no locant is needed in the name (e.g., propanal, not propan-1-al).

Note on carboxylic acids: Similarly, the carboxyl carbon is always C-1.